Insights into the influence of ethylene group orientation on the iron(iii) spin state in the spin crossover complex [FeIII(Sal2-trien)]+-Reference-Cited by-同舟云学术

Insights into the influence of ethylene group orientation on the iron(iii) spin state in the spin crossover complex [FeIII(Sal2-trien)]+

Published:2018 Issue:45 Volume:47 Page:16040-16043
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Blagov Maxim A.¹²³⁴⁵,Krapivin Vladimir B.¹²³⁴⁵,Simonov Sergey V.⁶²³^ORCID,Spitsyna Nataliya G.¹²³

Affiliation:

1. Institute of Problems of Chemical Physics RAS

2. Chernogolovka

3. Russia

4. Faculty of Fundamental Physical and Chemical Engineering

5. MSU

6. Institute of Solid State Physics RAS

Abstract

The DFT calculations of the spin crossover complex [Fe^III(Sal₂-trien)]⁺ with different conformations of ethylene groups were performed. The results explain the presence of disordered structures/transition states of the ethylene groups observed in the [Fe^III(Sal₂-trien)]⁺-type structures found in the CCDC database.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT03619E

Reference21 articles.

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