A room temperature spin crossover ionic liquid
Author:
Affiliation:
1. School of Chemistry
2. Dublin 4
3. Ireland
Abstract
Two new paramagnetic ionic liquids (ILs) comprising a mononuclear iron(iii) or manganese(iii) complex cation, charge balanced by a dicyanamide anion are reported which show a range of spin states including spin crossover.
Funder
Science Foundation Ireland
European Cooperation in Science and Technology
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT04264J
Reference40 articles.
1. M. A. Halcrow , Spin-crossover materials: properties and applications, John Wiley & Sons, 2013
2. Spin state switching in iron coordination compounds
3. Crystallography and spin-crossover. A view of breathing materials
4. Multifunctional Gels from Polymeric Spin-Crossover Metallo-Gelators
5. Organization of spin- and redox-labile metal centers into Langmuir and Langmuir–Blodgett films
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