Molecular and electronic structure of the dithiooxalato radical ligand stabilised by rare earth coordination-Reference-Cited by-同舟云学术

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Molecular and electronic structure of the dithiooxalato radical ligand stabilised by rare earth coordination

Published:2019 Issue:17 Volume:48 Page:5491-5495
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

McGuire Jake¹²³⁴,Wilson Bradley¹²³⁴,McAllister James¹²³⁴,Miras Haralampos N.¹²³⁴^ORCID,Wilson Claire¹²³⁴^ORCID,Sproules Stephen¹²³⁴^ORCID,Farnaby Joy H.¹²³⁴^ORCID

Affiliation:

1. WestCHEM School of Chemistry

2. University of Glasgow

3. Glasgow G12 8QQ

4. UK

Abstract

Coordinating rare earth ions to bis(dithiooxalato)nickel produces the first structurally characterised complexes possessing the elusive dithiooxalato radical ligand.

Funder

Engineering and Physical Sciences Research Council

University of Glasgow

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00688E

Reference36 articles.

1. CCXI.—The action of mercaptans on acid chlorides. Part I. Oxalyl chloride; the mono- and dithio-oxalates

2. Thio-oxalates: their ligand properties and coordination chemistry

3. Synthesis and Structure of a Binuclear [Bis(ethane-1,2-diamine)nickel(II)]-μ-(ethane-1,2-dithiolato)-[(ethane-1,2-dithiolato)Nickel(II)] Complex [Ni(en)2(μ-C2O2S2)Ni(C2O2S2)], and the Related 3,4-Dimercaptocyclobutene-1,2-dionato Complex

4. Structural and Physical Properties of the Ferromagnetic Tris-Dithiooxalato Compounds, A[MIICrIII(C2S2O2)3], with A+ = N(n-CnH2n+1)4+ (n = 3−5) and P(C6H5)4+ and MII = Mn, Fe, Co, and Ni

5. Metal complexes as ligands. III. Bonding interactions of the anionic metal dithiooxalate complexes with the coordinately unsaturated bis(triphenylphosphine)copper(I) and bis(triphenylphosphine)silver(I) complex cations

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