Investigation of the unique magnetic behaviours of isomers in a 1,2-dithiooxalato-bridged diiron(<scp>ii</scp>) complex-Reference-Cited by-同舟云学术

Investigation of the unique magnetic behaviours of isomers in a 1,2-dithiooxalato-bridged diiron(ii) complex

Published:2023 Issue:35 Volume:52 Page:12496-12503
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kanetomo Takuya¹^ORCID,Yokoyama Koki¹,Suzuki Yudai¹,Ida Hiromichi¹,Okazawa Atsushi²,Enomoto Masaya¹^ORCID

Affiliation:

1. Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan

2. Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 169-8555, Japan

Abstract

The compound [{Fe(TPA)}2(μ-dto)](ClO4)2 exhibits multi-step spin crossover behaviour with an irreversible structural change owing to the presence of isomers.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT01992F

Reference62 articles.

1. Thio-oxalates: their ligand properties and coordination chemistry

2. The dithiooxalate-bridged complex [Cr(C2O2S2)3(NiL)3][ClO4]3(L = racemic 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane): synthesis, crystal structure and magnetism

3. Chiral, Three-Dimensional Supramolecular Compounds: Homo- and Bimetallic Oxalate- and 1,2-Dithiooxalate-Bridged Networks. A Structural and Photophysical Study

4. Pentanuclear Heterobimetallic 3d-4f-Complexes – Structure and Luminescence

5. 1,2‐Dithiooxalato‐Bridged Heterobimetallic Complexes as Single‐Source Precursors for Ternary Metal Sulfide Semiconductors

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