How does methylviologen cation radical supply two electrons to the formate dehydrogenase in the catalytic reduction process of CO2 to formate?-Reference-Cited by-同舟云学术

How does methylviologen cation radical supply two electrons to the formate dehydrogenase in the catalytic reduction process of CO2 to formate?

Published:2020 Issue:33 Volume:22 Page:18595-18605
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Miyaji Akimitsu¹²³⁴,Amao Yutaka⁵⁶⁷⁴⁸^ORCID

Affiliation:

1. School of Materials and Chemical Technology

2. Tokyo Institute of Technology

3. Yokohama 226-8502

4. Japan

5. Graduate School of Science

6. Osaka City University

7. Osaka 558-8585

8. Research Centre of Artificial Photosynthesis (ReCAP)

Abstract

The two-electron supply process using single-electron reduced methylviologen as a co-enzyme in the reduction process of CO₂ to formate catalyzed by formate dehydrogenase from Candida boidinii was clarified by experimental and quantum chemical analyses.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP02665D

Reference58 articles.

1. Continuous enzymatic transformation in an enzyme membrane reactor with simultaneous NAD(H) regeneration

2. Dehydrogenases for the synthesis of chiral compounds

3. Regeneration of cofactors for use in biocatalysis

4. Formate dehydrogenase

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