In situ topotactic formation of an inorganic intergrowth bulk NiS/FeS@MgFe-LDH heterojunction to simulate CODH for the photocatalytic reduction of CO2

Author:

Li Yuexian1,Su Wenli2,Wang Xiaoyan1,Lu Jun13ORCID,Zhang Wenkai2,Wei Shuo4ORCID

Affiliation:

1. State Key Laboratory of Chemical Resource Engineering and College of Chemistry, Beijing University of Chemical Technology, P. Box 98, Beisanhuan East Road 15, Beijing 100029, P. R. China

2. Department of Physics and Applied Optics Beijing Area Major Laboratory, Center for Advanced Quantum Studies, Beijing Normal University, Xinjiekou Outside Street 19, Beijing 100875, China

3. Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, P. Box 98, Beisanhuan East Road 15, Beijing 100029, P. R. China

4. College of Chemistry, Beijing Normal University, Xinjiekou Outside Street 19, Beijing 100875, P. R. China

Abstract

By using of the structural memory effect of LDHs, an inorganic intergrowth bulk heterojunction NiS/FeS@MgFe-LDHs mimic active C-clusters [Ni–4Fe–4S] in Carbon monoxide dehydrogenase, in which unique photogenerated electron transfer channel encouraged carrier separation.

Funder

National Basic Research Program of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

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