Understanding the thermal dehydrochlorination reaction of 1-chlorohexane. Revealing the driving bonding pattern at the planar catalytic reaction center-Reference-Cited by-同舟云学术

Understanding the thermal dehydrochlorination reaction of 1-chlorohexane. Revealing the driving bonding pattern at the planar catalytic reaction center

Published:2015 Issue:77 Volume:5 Page:62946-62956
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

López Lina¹²³⁴⁵,Ruiz Pablo¹²³⁴⁵,Castro Manuela¹²³⁴⁵,Quijano Jairo¹²³⁴⁵,Duque-Noreña Mario⁶⁷⁸⁹¹⁰,Pérez Patricia⁶⁷⁸⁹¹⁰,Chamorro Eduardo⁶⁷⁸⁹¹⁰

Affiliation:

1. Universidad Nacional de Colombia

2. Laboratorio de Fisicoquímica Orgánica

3. Facultad de Ciencias

4. Medellín

5. Colombia

6. Universidad Andres Bello

7. Facultad de Ciencias Exactas

8. Departamento de Ciencias Quimicas

9. Millennium Nucleus Chemical Processes and Catalysis

10. 8370146 Santiago

Abstract

The gas-phase thermal decomposition of 1-chlorohexane is rationalized in terms of a two stage one step reaction mechanism.

Funder

Dirección de Investigación, Universidad Nacional de Colombia

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA10152B

Reference75 articles.

1. Heterolysis and the Pyrolysis of Alkyl Halides in the Gas Phase

2. Correlation of alkyl and polar groups in the gas-phase pyrolysis kinetics of .beta.-substituted ethyl chloride

3. Transition State for 1,2 Hydrogen Halide Elimination from Ethyl Halides

4. Rate Constants and Kinetic Isotope Effects for Unimolecular 1,2-HX or DX (X = F or Cl) Elimination from Chemically Activated CF3CFClCH3-d0, -d1, -d2, and -d3

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