Exceptionally high temperature spin crossover in amide-functionalised 2,6-bis(pyrazol-1-yl)pyridine iron(ii) complex revealed by variable temperature Raman spectroscopy and single crystal X-ray diffraction-Reference-Cited by-同舟云学术

Exceptionally high temperature spin crossover in amide-functionalised 2,6-bis(pyrazol-1-yl)pyridine iron(ii) complex revealed by variable temperature Raman spectroscopy and single crystal X-ray diffraction

Published:2021 Issue:34 Volume:50 Page:11843-11851
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Attwood Max¹^ORCID,Akutsu Hiroki²^ORCID,Martin Lee³^ORCID,Blundell Toby J.³^ORCID,Le Maguere Pierre⁴,Turner Scott S.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Surrey, Guildford, GU2 7XH, UK

2. Department of Chemistry, Graduate School of Science, Osaka University, 1-1 Machikaneyama, Toyonaka, Osaka 560-0043, Japan

3. School of Science and Technology, Nottingham Trent University, Clifton Lane, NG11 8NS, UK

4. Rigaku Americas Corporation, 9009 New Trails Drive, The Woodlands, TX 77381, USA

Abstract

A new amide substituted ligand based on 2,6-bis(pyrazol-1-yl)pyridine yields two novel Fe(ii) complexes with very high spin crossover transition temperatures.

Funder

University of Surrey

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT01743H

Reference31 articles.

1. The spin-states and spin-transitions of mononuclear iron(II) complexes of nitrogen-donor ligands

2. Decoupled Spin Crossover and Structural Phase Transition in a Molecular Iron(II) Complex

3. Relationship between the Molecular Structure and Switching Temperature in a Library of Spin-Crossover Molecular Materials