Room temperature spin crossover properties in a series of mixed-anion Fe(NH2trz)3(BF4)2−x(SiF6)x/2 complexes-Reference-Cited by-同舟云学术

Room temperature spin crossover properties in a series of mixed-anion Fe(NH₂trz)₃(BF₄)_2−x(SiF₆)_x/2 complexes

Published:2024 Issue:15 Volume:53 Page:6830-6838
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Yang Xinyu¹,Enriquez-Cabrera Alejandro¹^ORCID,Jacob Kane¹,Coppel Yannick¹^ORCID,Salmon Lionel¹^ORCID,Bousseksou Azzedine¹

Affiliation:

1. LCC, CNRS & Université de Toulouse (UPS, INP), 31077 Toulouse, France

Abstract

A series of mixed-anion Fe(NH2trz)3(BF4)2−x(SiF6)x/2 complexes presenting abrupt spin crossover behaviour with a narrow hysteresis loop just above room temperature is obtained by coordination reaction or solid–liquid post synthetic modification.

Funder

H2020 European Research Council

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00267A

Reference46 articles.

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2. Emerging trends in spin crossover (SCO) based functional materials and devices

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4. Switchable cobalt coordination polymers: Spin crossover and valence tautomerism

5. Spin-crossover in iron(ii)-Schiff base complexes

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