Photocatalytic borylcyclopropanation of α-boryl styrenes
Author:
Affiliation:
1. Institute of Transformative Bio-Molecules (WPI-ITbM) and Department of Molecular and Macromolecular Chemistry
2. Graduate School of Engineering
3. Nagoya University
4. Nagoya 464-8601
5. Japan
Abstract
A diastereoselective borylcyclopropanation of α-MIDA-boryl styrenes is developed using 4CzIPN as a catalyst under visible-light irradiation. The scope of this photocatalytic method is explored, and the utility of the resulting doubly borylated cyclopropanes is demonstrated by the selective transformations of one of the two boryl groups.
Funder
Nagoya University
Japan Society for the Promotion of Science
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/QO/C9QO00197B
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