Visible light induced cyclopropanation of dibromomalonates with alkenes via double-SET by photoredox catalysis

Author:

Zhang Yanbin1234,Qian Rong56784,Zheng Xingliang910114,Zeng Yi910114,Sun Jing1234,Chen Yiyong1234,Ding Aishun1234,Guo Hao123412

Affiliation:

1. Department of Chemistry

2. Fudan University

3. Shanghai

4. P. R. China

5. Shanghai Mass Spectrometry Center

6. Shanghai Institute of Ceramics

7. Chinese Academy of Sciences

8. Shanghai 200050

9. Institute of Chemistry & Biological Engineering

10. Changsha University of Science and Technology

11. Changsha 410114

12. Key Laboratory of Organofluorine Chemistry

Abstract

We report herein a visible light induced generation of a carbanion via double-SET and its application in cyclopropanation of electron-deficient alkenes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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