De novo synthesis of mesoporous photoactive titanium(iv)–organic frameworks with MIL-100 topology

Author:

Castells-Gil Javier123ORCID,M. Padial Natalia12345ORCID,Almora-Barrios Neyvis123ORCID,da Silva Ivan6789ORCID,Mateo Diego1011123,Albero Josep1011123,García Hermenegildo1011123ORCID,Martí-Gastaldo Carlos123ORCID

Affiliation:

1. Universidad de Valencia (ICMol)

2. Paterna

3. Spain

4. Department of Chemistry

5. The Scripps Research Institute

6. ISIS Facility

7. Rutherford Appleton Laboratory

8. Didcot

9. UK

10. Instituto Universitario de Tecnología Química CSIC-UPV

11. Universitat Politècnica de València

12. Valencia

Abstract

The development of new titanium frameworks remains limited by the difficulties in forming persistent Ti clusters amenable to the isoreticular approach. MIL-100(Ti) combines a mesoporous structure with excellent chemical stability and photoactivity from the reticulation of Ti33-O) metal-oxo clusters.

Funder

Ministerio de Economía y Competitividad

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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