Hydrolytically stable fluorinated metal-organic frameworks for energy-efficient dehydration

Author:

Cadiau Amandine1ORCID,Belmabkhout Youssef1ORCID,Adil Karim1ORCID,Bhatt Prashant M.1,Pillai Renjith S.1ORCID,Shkurenko Aleksander1ORCID,Martineau-Corcos Charlotte23ORCID,Maurin Guillaume4ORCID,Eddaoudi Mohamed1ORCID

Affiliation:

1. King Abdullah University of Science and Technology (KAUST), Division of Physical Science and Engineering (PSE), Advanced Membrane and Porous Materials (AMPM), Functional Materials Design, Discovery and Development (FMD3), Thuwal 23955-6900, Kingdom of Saudi Arabia.

2. Institut Lavoisier de Versailles (ILV), UMR CNRS 8180, Université de Versailles St–Quentin en Yvelines (UVSQ), 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France.

3. CEMHTI-CNRS, UPR 3079, 1D Avenue de la Recherche Scientifique, 45071 Orléans Cedex 2, France.

4. Institut Charles Gerhardt Montpellier (UMR CNRS 5253), Université Montpellier, Place Eugène Bataillon, 34095 Montpellier Cedex 05, France.

Abstract

Drying natural gas efficiently Natural gas must be purified before it can be transported. The preparation process also includes a drying step to remove water. Microporous adsorbents such as zeolites are used for this purpose, but they often need to be heated to temperatures up to 250°C to remove the water so that they can be reused. Cadiau et al. describe a fluorinated metal-organic framework containing nickel metal centers that can remove water from gas streams but that can be regenerated by heating to only 105°C. Science , this issue p. 731

Funder

King Abdullah University of Science and Technology

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference48 articles.

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