One-pot, two-step desymmetrization of symmetrical benzils catalyzed by the methylsulfinyl (dimsyl) anion-Reference-Cited by-同舟云学术

One-pot, two-step desymmetrization of symmetrical benzils catalyzed by the methylsulfinyl (dimsyl) anion

Published:2014 Issue:30 Volume:12 Page:5733-5744
ISSN:1477-0520
Container-title:Org. Biomol. Chem.
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Ragno Daniele¹²³,Bortolini Olga¹²³,Giovannini Pier Paolo¹²³,Massi Alessandro¹²³,Pacifico Salvatore¹²³,Zaghi Anna¹²³

Affiliation:

1. Dipartimento di Scienze Chimiche e Farmaceutiche

2. Laboratorio di Chimica Organica

3. 44121 Ferrara, Italy

Abstract

Symmetrical-to-unsymmetrical benzil conversion is realized by a one-pot two-step procedure involving a chemoselective cross-benzoin reaction followed by microwave-assisted oxidation of the benzoylated benzoin intermediate.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/OB/C4OB00759J

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