A novel route to unsymmetrical disubstituted ureas and thioureas by HMPA catalyzed reductive alkylation with trichlorosilane-Reference-Cited by-同舟云学术

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A novel route to unsymmetrical disubstituted ureas and thioureas by HMPA catalyzed reductive alkylation with trichlorosilane

Published:2020 Issue:3 Volume:7 Page:472-481
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Ran Xiaoyun¹²³⁴,Long Yan¹²³⁴,Yang Sheng¹²³⁴,Peng Changjiang¹²³⁴,Zhang Yuanyuan¹²³⁴,Qian Shan⁵²³⁴,Jiang Zhenju¹²³⁴,Zhang Xiaomei¹²³⁴^ORCID,Yang Lingling⁵²³⁴,Wang Zhouyu¹²³⁴^ORCID,Yu Xiaoqi¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Xihua University

3. Chengdu

4. China

5. Department of Pharmaceutics Engineering

Abstract

A HMPA catalyzed reductive alkylation of ureas and thioureas with trichlorosilane under mild reaction conditions has been developed.

Funder

National Natural Science Foundation of China

Education Department of Sichuan Province

Xihua University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/QO/C9QO01321K

Reference64 articles.

1. Thioureas as Building Blocks for the Generation of Heterocycles and Compounds with Pharmacological Activity: An Overview

2. Ureas: Applications in Drug Design

3. Anion coordinated capsules and pseudocapsules of tripodal amide, urea and thiourea scaffolds

4. Anion binding with urea and thiourea derivatives

5. Urea, a true uremic toxin: the empire strikes back

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1. N, N'-disubstituted Ureas as Novel Antiplatelet Agents: Synthesis, Pharmacological Evaluation and In Silico Studies;Current Medicinal Chemistry;2024-01-17

2. Synthesis of N-monosubstituted ureas in a mixture of choline chloride and aluminium nitrate as a simple, efficient, and selective process;Monatshefte für Chemie - Chemical Monthly;2023-10-10

3. Synthesis of N-monosubstituted ureas in a mixture of choline chloride and Aluminium nitrate as a green and selective process;2023-02-03

4. Synthesis of Complex Ureas with Brominated Heterocyclic Intermediates;ChemistrySelect;2023-02

5. Palladium-Catalyzed Aerobic Oxidative Carbonylation of Amines Enables the Synthesis of Unsymmetrical N,N′-Disubstituted Ureas;Synlett;2021-05-06

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