Exo-bonded six-membered heterocycle in the crystal structures of RE7Co2Ge4(RE = La

Exo-bonded six-membered heterocycle in the crystal structures of RE7Co2Ge4(RE = La–Nd)

Published:2016 Issue:46 Volume:45 Page:18522-18531
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ponou Siméon¹²³⁴⁵,Lidin Sven¹²³⁴⁵

Affiliation:

1. Centre for Analysis and Synthesis

2. Department of Chemistry

3. Lund University

4. SE-22100 Lund

5. Sweden

Abstract

The stability of the heterocyclic {Co₄Ge₆} clusters in RE₇Co₂Ge₄(RE = La–Nd) is determined by strong interactions with the surrounding RE atoms in the structures.

Funder

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT03302D

Reference55 articles.

1. G. J. Miller , Metal-Rich Compounds of the d-Metals, in Comprehensive Inorganic Chemistry II, ed. J. Reedijk and K. Poeppelmeier, Elsevier, Amsterdam, 2nd edn, 2013, pp. 311–357, 10.1016/B978-0-08-097774-4.00214-X

2. Synergistic Geometrical and Electronic Features in the Intermetallic Phases Ca2AgM2, Ca2MgM2, and Ca2GaM2(M= Pd, Pt)

3. Origins of Superstructure Ordering and Incommensurability in Stuffed CoSn-Type Phases

4. Linear Metal Chains in Ca2M2X (M = Pd, Pt; X = Al, Ge): Origin of the Pairwise Distortion and Its Role in the Structure Stability

5. Zintl Phases: Transitions between Metallic and Ionic Bonding

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