Polar‐Covalent Bonding Beyond the Zintl Picture in Intermetallic Rare‐Earth Germanides
Author:
Affiliation:
1. Dipartimento di Chimica e Chimica IndustrialeUniversità degli Studi di Genova Via Dodecaneso 31 16146 Genova Italy
2. Max-Planck-Institut für Chemische Physik fester Stoffe Nöthnitzer Straße 40 01187 Dresden Germany
Publisher
Wiley
Subject
General Chemistry,Catalysis,Organic Chemistry
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/chem.201900510
Reference59 articles.
1. Unusual Electronic and Bonding Properties of the Zintl Phase Ca5Ge3 and Related Compounds. A Theoretical Analysis1
2. Structure and Bonding of an Intergrowth Phase Ca 7 Ag 2+ x Ge 7– x ( x ≈ 2/3) Featuring a Zintl‐Type Polyanionic Chain
3. Exo-bonded six-membered heterocycle in the crystal structures of RE7Co2Ge4(RE = La–Nd)
4. Vacancy Ordering as a Driving Factor for Structural Changes in Ternary Germanides: The New R2Zn1–xGe6 Series of Polar Intermetallics (R = Rare-Earth Metal)
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