Active site tuning based on pseudo-binary alloys for low-temperature acetylene semihydrogenation

Author:

Ma Jiamin1,Xing Feilong1ORCID,Shimizu Ken-ichi1ORCID,Furukawa Shinya1ORCID

Affiliation:

1. Institute for Catalysis, Hokkaido University, Sapporo 001-0021, Japan

Abstract

The size of Ni–Ni ensembles can be finely tuned by Cu doping to the Ni sites of Ni3Ga. The (Ni0.8Cu0.2)3Ga/TiO2 catalyst exhibited outstandingly high catalytic activity, selectivity, and stability in acetylene semihydrogenation even at 150 °C.

Funder

Japan Society for the Promotion of Science

Core Research for Evolutional Science and Technology

Precursory Research for Embryonic Science and Technology

Publisher

Royal Society of Chemistry (RSC)

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