Pronounced effects of the densities of threaded rings on the strain-dependent Poisson's ratio of polyrotaxane gels with movable cross-links

Author:

Tanaka Akira12345,Kato Kazuaki678910ORCID,Ito Kohzo678910ORCID,Urayama Kenji12345ORCID

Affiliation:

1. Department of Macromolecular Science and Engineering

2. Kyoto Institute of Technology

3. Sakyo-ku

4. Kyoto 606-8585

5. Japan

6. Department of Advanced Materials Science

7. School of Frontier Sciences

8. The University of Tokyo

9. 5-1-5 Kashiwanoha

10. Kashiwa

Abstract

The density of threaded ring molecules in polyrotaxane (PR) chains influences pronouncedly the equilibrium Poisson's ratio of PR gels where the cross-linked ring molecules are slidable along the network strands.

Funder

Cabinet Office, Government of Japan

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Chemistry

Reference32 articles.

1. Polymeric Rotaxanes

2. Cyclodextrin Rotaxanes and Polyrotaxanes

3. K. Ito , K.Mayumi and K.Kato , Polyrotaxane and Slide-Ring Materials , The Royal Society of Chemistry , Cambridge, UK , 2016

4. The Polyrotaxane Gel: A Topological Gel by Figure-of-Eight Cross-links

5. A multitude of macromolecules

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