Time–strain inseparability in multiaxial stress relaxation of supramolecular gels formed via host–guest interactions

Author:

Kimura Takuro1,Aoyama Takuma1,Nakahata Masaki2ORCID,Takashima Yoshinori3ORCID,Tanaka Motomu45ORCID,Harada Akira6ORCID,Urayama Kenji17ORCID

Affiliation:

1. Department of Macromolecular Science and Engineering, Kyoto Institute of Technology, Sakyo-ku, Kyoto 606-8585, Japan

2. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 560-8531 Osaka, Japan

3. Institute for Advanced Co-Creation Studies, Osaka University, Suita, Osaka 565-0871, Japan

4. Center for Integrative Medicine and Physics, Institute for Advanced Study, Kyoto University, 606-8501 Kyoto, Japan

5. Physical Chemistry of Biosystems, Institute of Physical Chemistry, Heidelberg University, D69120 Heidelberg, Germany

6. The Institute of Scientific and Industrial Research, Osaka University, Ibaraki, Osaka 567-0047, Japan

7. Department of Material Chemistry, Graduate School of Engineering, Kyoto University, 615-8510 Kyoto, Japan

Abstract

Time and strain effects on stress are not separable in supramolecular gels utilizing host–guest interactions in contrast to a dual cross-link gel with covalent and transient cross-links in which the separability was validated by the same assessment.

Funder

Cabinet Office, Government of Japan

Japan Society for the Promotion of Science

Nakatani Foundation for Advancement of Measuring Technologies in Biomedical Engineering

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Chemistry

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