Enhanced photoinduced mass migration in supramolecular azopolymers by H-bond driven positional constraint

Author:

Borbone Fabio12ORCID,Oscurato Stefano Luigi23ORCID,Del Sorbo Salvatore2ORCID,Pota Filippo1ORCID,Salvatore Marcella3ORCID,Reda Francesco3ORCID,Maddalena Pasqualino23ORCID,Centore Roberto1ORCID,Ambrosio Antonio2ORCID

Affiliation:

1. Department of Chemical Sciences, University of Napoli Federico II, Complesso Universitario di Monte Sant’Angelo, Via Cintia, Naples 80126, Italy

2. CNST@POLIMI – Fondazione Istituto Italiano di Tecnologia, Via Pascoli 70, Milan 20133, Italy

3. Department of Physics E. Pancini, University of Napoli Federico II, Complesso Universitario di Monte Sant’Angelo, Via Cintia, Naples 80126, Italy

Abstract

SRG inscription on azopolymers films is strongly enhanced by constrained azobenzene–chain interaction established through double H-bond supramolecular synthon. Selective removal of azobenzene from patterned samples is possible by solvent rinse.

Funder

Fondazione Cariplo

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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