Interfacial stability and ionic conductivity enhanced by dopant segregation in eutectic ceramics: the role of Gd segregation in doped CeO2/CoO and CeO2/NiO interfaces

Author:

Orera Alodia1234ORCID,Wang Funing56478,Ferreiro-Vila Elías910114,Serrano-Zabaleta Sonia1234,Larrañaga Aitor1213144ORCID,Laguna-Bercero Miguel A.1234ORCID,Dickey Elizabeth C.15161718ORCID,Rivadulla Francisco910114ORCID,Muñoz M. Carmen564ORCID,Larrea Ángel1234ORCID

Affiliation:

1. Instituto de Ciencia de Materiales de Aragón

2. CSIC – U. Zaragoza

3. E-50.018 Zaragoza

4. Spain

5. Instituto de Ciencia de Materiales de Madrid, ICMM-CSIC

6. E-28049 Madrid

7. School of Physics

8. Shandong University

9. CiQUS, Centro de Investigación en Química Biolóxica e Materiais Moleculares

10. Universidade de Santiago de Compostela

11. Santiago de Compostela 15782

12. SGIker, Servicios Generales de Investigación

13. Universidad del País Vasco (UPV/EHU)

14. 48080 Bilbao

15. Department of Materials Science & Engineering

16. North Carolina State University

17. Raleigh

18. USA

Abstract

Ionic charge balance at the interface of Gd-doped CeO2/CoO eutectic ceramics produces Gd segregation and increases the interfacial ionic conductivity.

Funder

Ministerio de Economía y Competitividad

Xunta de Galicia

China Scholarship Council

European Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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