A more sustainable isothiocyanate synthesis by amine catalyzed sulfurization of isocyanides with elemental sulfur-Reference-Cited by-同舟云学术

A more sustainable isothiocyanate synthesis by amine catalyzed sulfurization of isocyanides with elemental sulfur

Published:2021 Issue:5 Volume:11 Page:3134-3142
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Nickisch R.¹²³⁴^ORCID,Conen P.¹²³⁴,Gabrielsen S. M.¹²³⁴^ORCID,Meier M. A. R.¹²³⁴⁵^ORCID

Affiliation:

1. Institute of Organic Chemistry (IOC)

2. Karlsruhe Institute of Technology (KIT)

3. 76131 Karlsruhe

4. Germany

5. Institute of Biological and Chemical Systems-Functional Molecular Systems (IBCS-FMS)

Abstract

Isothiocyanates were snythesized in a more sustainable manner by sulfurization of isocyanides with elemental sulfur using catalytic amounts of DBU (down to 2 mol%).

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/RA/D0RA10436A

Reference95 articles.

1. Isothiocyanates in the chemistry of heterocycles

2. Isothiocyanates in Heterocyclic Synthesis

3. Resin-Bound Isothiocyanates and Their Synthetic Equivalents as Intermediates for the Solid-Phase Synthesis of Substituted Thiophenes

4. Iron-Catalyzed Tandem Reactions of 2-Halobenzenamines with Isothiocyanates Leading to 2-Aminobenzothiazoles

5. Tandem regioselective synthesis of tetrazoles and related heterocycles using iodine

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