A versatile access to vicinal diamine motifs by highly anti-selective asymmetric vinylogous Mannich reactions: an efficient total synthesis of (+)-absouline

Author:

Ye Jian-Liang12345,Chen Hang12345,Zhang Yu-Feng12345,Huang Pei-Qiang12345

Affiliation:

1. Department of Chemistry and Fujian Provincial Key Laboratory of Chemical Biology

2. iChEM (Collaborative Innovation Center of Chemistry for Energy Materials)

3. College of Chemistry and Chemical Engineering

4. Xiamen University

5. Xiamen

Abstract

An anti-stereoselective vinylogous Mannich reaction between 2-TBSO-pyrrole and N-tert-butanesulfinyl imines and its application to the efficient synthesis of (+)-absouline were reported.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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