The addition of Grignard reagents to carbodiimides. The synthesis, structure and potential utilization of magnesium amidinates-Reference-Cited by-同舟云学术

The addition of Grignard reagents to carbodiimides. The synthesis, structure and potential utilization of magnesium amidinates

Published:2019 Issue:16 Volume:48 Page:5335-5342
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Chlupatý Tomáš¹²³⁴⁵^ORCID,Bílek Michal¹²³⁴⁵,Merna Jan⁶²⁷⁸⁵,Brus Jiří⁹¹⁰¹¹⁵^ORCID,Růžičková Zdeňka¹²³⁴⁵,Strassner Thomas¹²¹³¹⁴¹⁵¹⁶^ORCID,Růžička Aleš¹²³⁴⁵^ORCID

Affiliation:

1. Department of General and Inorganic Chemistry

2. Faculty of Chemical Technology

3. University of Pardubice

4. Pardubice

5. Czech Republic

6. Institute of Chemical Technology

7. Department of Polymers

8. CZ-166 28 Prague 6

9. Institute of Macromolecular Chemistry

10. Czech Academy of Sciences

11. Praha 6

12. Physical Organic Chemistry

13. Faculty of Chemistry and Food Chemistry

14. Technical University Dresden

15. D-01062 Dresden

16. Germany

Abstract

Magnesium amidinates of different composition were prepared from carbodiimides and Grignard reagents with the assistance of the solvent and substrate dependent Schlenk equilibria.

Funder

Grantová Agentura České Republiky

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00880B

Reference55 articles.

1. Grignard Reagents , ed. R. S. Richey , John Wiley & Sons , New York , 2000 , pp. 185–275

2. Condensation of Certain Esters by Means of Diethylaminomagnesium Bromide1,2

3. The Lightest Metals: Science and Technology from Lithium to Calcium , ed. T. P. Hanusa , Wiley , Chichester , 2015

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