Isocyanate deoxygenation by a molecular magnesium silanide-Reference-Cited by-同舟云学术

Isocyanate deoxygenation by a molecular magnesium silanide

Published:2022 Issue:1 Volume:51 Page:136-144
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Okokhere-Edeghoghon Bibian¹^ORCID,Neale Samuel E.¹^ORCID,Hill Michael S.¹^ORCID,Mahon Mary F.¹,McMullin Claire L.¹

Affiliation:

1. Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK

Abstract

A molecular magnesium silanide is shown through a combined synthetic and computational study to effect siloxide formation and isocyanate deoxgenation via the initial formation of magnesium silamidate intermediates.

Funder

Petroleum Technology Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT03775G

Reference30 articles.

1. A new method for the reduction of isocyanates to isocyanides

2. Deoxygenation of isocyanates to isonitriles

3. Reactions of an Isolable Dialkylsilylene with Carbon Dioxide and Related Heterocumulenes

4. A Germylene/Borane Lewis Pair and the Remarkable C=O Bond Cleavage Reaction toward Isocyanate and Ketone Molecules

5. A stable ring-expanded NHC-supported copper boryl and its reactivity towards heterocumulenes

Cited by 4 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Synthesis of asymmetrical β-diketiminate magnesium methyl complexes and their catalytic application in cyanosilylation of ketones;Journal of Molecular Structure;2024-01

2. Investigation of four Cd(ii) sulfonate complexes: crystal structure, Hirshfeld surface analysis, thermogravimetric and spectroscopic properties;CrystEngComm;2023

3. Coordination Chemistry of Main Group Metals with Organic Isocyanides;European Journal of Inorganic Chemistry;2022-09-13

4. Diverse reactivity of a magnesium silanide toward ketones;Chemical Communications;2022