Co-crystallization of racemic amino acids with ZnCl2: an investigation of chiral selectivity upon coordination to the metal centre-Reference-Cited by-同舟云学术

Co-crystallization of racemic amino acids with ZnCl2: an investigation of chiral selectivity upon coordination to the metal centre

Published:2020 Issue:34 Volume:22 Page:5613-5619
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Shemchuk Oleksii¹²³⁴⁵^ORCID,Grepioni Fabrizia¹²³⁴⁵^ORCID,Braga Dario¹²³⁴⁵^ORCID

Affiliation:

1. Molecular Crystal Engineering Laboratory

2. Dipartimento di Chimica “G. Ciamician”

3. Università di Bologna

4. 40126 Bologna

5. Italy

Abstract

A preference for racemic vs. meso-crystal formation has been observed upon the cocrystallization of dl-amino acids with ZnCl₂, as a result of homo vs. heterochiral competition.

Funder

Università di Bologna

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CE/D0CE00775G

Reference45 articles.

1. Solubility of chiral species as function of the enantiomeric excess

2. Chiral Symmetry Breaking During Crystallization: Complete Chiral Purity Induced by Nonlinear Autocatalysis and Recycling

3. Enabling Direct Preferential Crystallization in a Stable Racemic Compound System

4. Pitfalls and rewards of preferential crystallization

5. Crystal engineering of the composition of pharmaceutical phases. Do pharmaceutical co-crystals represent a new path to improved medicines?

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