Mechanistic insights into HCO2H dehydrogenation and CO2 hydrogenation catalyzed by Ir(Cp*) containing tetrahydroxy bipyrimidine ligand: the role of sodium and proton shuttle-Reference-Cited by-同舟云学术

Mechanistic insights into HCO2H dehydrogenation and CO2 hydrogenation catalyzed by Ir(Cp*) containing tetrahydroxy bipyrimidine ligand: the role of sodium and proton shuttle

Published:2018 Issue:47 Volume:47 Page:17020-17031
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Wonglakhon Tanakorn¹²³⁴⁵^ORCID,Surawatanawong Panida¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry and Center of Excellence for Innovation in Chemistry

2. Faculty of Science

3. Mahidol University

4. Bangkok 10400

5. Thailand

Abstract

Catalytic HCO₂H dehydrogenation by Ir(Cp*) tetrahydroxy bipyrimidine is influenced not only by the protonation states but also by the involvement of Na⁺ and the availability of HCO₂H as a proton shuttle.

Funder

Thailand Research Fund

Faculty of Science, Mahidol University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT03283A

Reference60 articles.

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2. C. Ziebart and M.Beller , Hydrogenation and Related Reductions of Carbon Dioxide with Molecular Catalysts , Springer , Berlin, Heidelberg , 2014