Cp* non-innocence and the implications of (η4-Cp*H)Rh intermediates in the hydrogenation of CO2, NAD+, amino-borane, and the Cp* framework – a computational study-Reference-Cited by-同舟云学术

Cp* non-innocence and the implications of (η⁴-Cp*H)Rh intermediates in the hydrogenation of CO₂, NAD⁺, amino-borane, and the Cp* framework – a computational study

Published:2023 Issue:5 Volume:52 Page:1182-1187
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Pal Shrinwantu¹^ORCID

Affiliation:

1. Coordination Chemistry and Catalysis Unit, Okinawa Institute of Science and Technology, 1919-1 Tancha, Onna-son, Okinawa, 904-0495, Japan

Abstract

In hydrogenation mediated by half-sandwich complexes of Rh, Cp*Rh(iii)–H intermediates are critical hydride-delivery agents.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D2DT03611H

Reference61 articles.

1. Pentamethylcyclopentadienylrhodium and -iridium halides. I. Synthesis and properties

2. J.Okuda and T.Eberle , in Metallocenes , Wiley-VCH Verlag GmbH , Weinheim, Germany , 2008 , pp. 415–453

3. Base-Free Iridium-Catalyzed Hydrogenation of Esters and Lactones

4. Hydrogenation of Carboxylic Acids Catalyzed by Half-Sandwich Complexes of Iridium and Rhodium

5. Ambient-pressure hydrogenation of ketones and aldehydes by a metal-ligand bifunctional catalyst [Cp*Ir(2,2′-bpyO)(H2O)] without using base

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