Stoichiometric control: 8- and 10-coordinate Ln(hfac)3(bpy) and Ln(hfac)3(bpy)2 complexes of the early lanthanides La–Sm
Author:
Affiliation:
1. Department of Chemistry
2. University of Guelph
3. Guelph
4. Canada
5. Louisiana Tech. University
6. Ruston
7. USA
8. Indiana University Bloomington
9. Bloomington
10. FreeLance Crystallography
11. London
Abstract
Solution and mechanochemistry are used to obtain 8- and 10-coordinate complexes of the lanthanides La–Sm Ln(hfac)3(bpy)X(X = 1, 2).
Funder
Natural Sciences and Engineering Research Council of Canada
Division of Graduate Education
Division of Chemistry
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT03286F
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4. Syntheses and crystal structures of anhydrous Ln(hfac)3(monoglyme). Ln = La, Ce, Pr, Sm, Eu, Gd, Tb, Dy, Er, Tm
5. (μ-1,2-Dimethoxyethane-κ2O:O′)bis[(1,2-dimethoxyethane-κ2O,O′)tris(1,1,1,5,5,5-hexafluoro-4-oxopent-2-en-2-olato-κ2O,O′)cerium(III)]
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