Lanthanide(iii) (Er/Ho) coordination polymers for a photocatalytic CO2 cycloaddition reaction

Author:

Alzard Reem H.1,Siddig Lamia A.1,Abdelhamid Abdalla S.1,Paz Alejandro Perez1,Nguyen Ha L.23ORCID,Sethupathi K.4,Sreejith P. K.4,Alzamly Ahmed1ORCID

Affiliation:

1. Department of Chemistry, UAE University, P.O. Box 15551, Al-Ain, United Arab Emirates

2. Department of Chemistry, University of California Berkeley; Kavli Energy Nanoscience Institute at UC Berkeley; and Berkeley Global Science Institute, Berkeley, California 94720, USA

3. Joint UAEU–UC Berkeley Laboratories for Materials Innovations, United Arab Emirates University, Al-Ain 15551, United Arab Emirates

4. Low Temperature Physics Laboratory, Department of Physics, Indian Institute of Technology Madras, Chennai 600036, India

Abstract

Ribbon-like structure photocatalysts composed of 4-aminobenzoate and Ho/Er were used for the cycloaddition of CO2 to epoxides under simulated UV light. The catalysts attained up to 99.9% conversion yields of different cyclic carbonates.

Funder

National Water Center, United Arab Emirates University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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