Selective C–H halogenation over hydroxylation by non-heme iron(iv)-oxo
Author:
Affiliation:
1. Department of Chemistry
2. IIT Bombay
3. Mumbai-400076
4. India
5. University of Grenoble Alpes
6. LCBM/PMB and CEA
7. IRTSV/CBM/PMB and CNRS
8. 38000 Grenoble
9. France
Abstract
Synthetic non-heme iron-oxo and iron-halide complexes promote selective halogenation of the sp3-C–H bonds via hydrogen atom abstraction and halide rebound phenomenon.
Funder
Science and Engineering Research Board
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC02053A
Reference82 articles.
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5. Structural and Functional Aspects of Metal Sites in Biology
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