DMSO as oxidant and sulfenylating agent for metal-free oxidation and methylthiolation of alcohol-containing indoles
Author:
Affiliation:
1. Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education (MOE)
2. Hangzhou Normal University
3. Hangzhou 311121
4. P. R. China
5. State Key Laboratory for Oxo Synthesis and Selective Oxidation
Abstract
A new methylthiolation protocol was successfully established for the synthesis of substituted indoles bearing 3-methylthioether moiety, in which new C–S bond and C=O bond were formed using dimethyl sulfoxide as the sulfur source under mild conditions.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA03606B
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