Comment on “The oxidation state in low-valent beryllium and magnesium compounds” by M. Gimferrer, S. Danés, E. Vos, C. B. Yildiz, I. Corral, A. Jana, P. Salvador and D. M. Andrada, <i>Chem. Sci.</i> 2022, <b>13</b>, 6583-Reference-Cited by-同舟云学术

Comment on “The oxidation state in low-valent beryllium and magnesium compounds” by M. Gimferrer, S. Danés, E. Vos, C. B. Yildiz, I. Corral, A. Jana, P. Salvador and D. M. Andrada, Chem. Sci. 2022, 13, 6583

Published:2023 Issue:2 Volume:14 Page:379-383
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Pan Sudip¹^ORCID,Frenking Gernot¹²³^ORCID

Affiliation:

1. Fachbereich Chemie, Philipps-Universität Marburg, Marburg, Germany

2. Donostia International Physics Center (DIPC), 20018 San Sebastian, Spain

3. Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, China

Abstract

Metal–ligand bonds in M(cAACDip)2 (M = Be, Mg) are best described with dative bonds between neutral ligands L⇄M⇄L but not with charged species L(−1)→E(+2)←L(−1) as previously stated. The oxidation state of the metals is zero but not +2.

Funder

Nanjing Tech University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC04231B

Reference48 articles.

1. The oxidation state in low-valent beryllium and magnesium compounds

2. Neutral zero-valent s-block complexes with strong multiple bonding

3. Chemically Non-Innocent Cyclic (Alkyl)(Amino)Carbenes: Ligand Rearrangement, C−H and C−F Bond Activation