Thioether-terminated nickel(ii) coordination clusters with {Ni6} horseshoe- and {Ni8} rollercoaster-shaped cores
Author:
Affiliation:
1. Institut für Anorganische Chemie
2. RWTH Aachen University
3. 52074 Aachen
4. Germany
5. Chemistry Department
6. Iowa State University
7. Ames
8. USA
9. Jülich-Aachen Research Alliance (JARA-FIT) and Peter Grünberg Institute (PGI-6)
Abstract
We report two polynuclear nickel(ii) compounds whose supramolecular structures are controlled by small inorganic templating anions and π-conjugated Schiff-base ligands (L·SMe3− and HL·SMe2−) with peripheral, structurally exposed methylthioether groups.
Funder
European Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/QI/C5QI00278H
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