Thioether-terminated nickel(ii) coordination clusters with {Ni6} horseshoe- and {Ni8} rollercoaster-shaped cores

Author:

Schmitz Sebastian1234,van Leusen Jan1234,Ellern Arkady5678,Kögerler Paul12349ORCID,Monakhov Kirill Yu.1234

Affiliation:

1. Institut für Anorganische Chemie

2. RWTH Aachen University

3. 52074 Aachen

4. Germany

5. Chemistry Department

6. Iowa State University

7. Ames

8. USA

9. Jülich-Aachen Research Alliance (JARA-FIT) and Peter Grünberg Institute (PGI-6)

Abstract

We report two polynuclear nickel(ii) compounds whose supramolecular structures are controlled by small inorganic templating anions and π-conjugated Schiff-base ligands (L·SMe3− and HL·SMe2−) with peripheral, structurally exposed methylthioether groups.

Funder

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference95 articles.

1. Modern Surface Organometallic Chemistry, ed. J.-M. Basset, R. Psaro, D. Roberto and R. Ugo, Wiley-VCH, Weinheim, 2009

2. Molecular spintronics using single-molecule magnets

3. Effect of Anchoring Groups on Single Molecule Charge Transport through Porphyrins

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