Fluorine-directed 1,2-trans glycosylation of rare sugars
Author:
Affiliation:
1. Institute for Organic Chemistry and Excellence Cluster EXC 1003 “Cells in Motion”
2. Westfälische Wilhelms-Universität Münster
3. 48149 Münster
4. Germany
Abstract
To reconcile the urgent need to access well defined β-configured 2,6-di-deoxypyranose analogues for chemical biology, with the intrinsic α-selectivity of the native system, the directing role of fluorine at C2 has been explored.
Funder
European Research Council
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/OB/C6OB00025H
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