The catalytic activities and magnetic behaviours of rare μ3-chlorido and μ1,1,1-azido bridged defective dicubane tetranuclear Mn(ii) complexes-Reference-Cited by-同舟云学术

The catalytic activities and magnetic behaviours of rare μ3-chlorido and μ1,1,1-azido bridged defective dicubane tetranuclear Mn(ii) complexes

Published:2019 Issue:25 Volume:48 Page:9342-9356
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Das Avijit¹²³⁴⁵,Chakraborty Maharudra¹²³⁴⁵,Maity Souvik¹²³⁴⁵,Ghosh Ashutosh¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. University College of Science

3. University of Calcutta

4. Kolkata 700009

5. India

Abstract

A μ₃-chlorido and a μ_1,1,1-azido bridged defective dicubane tetranuclear Mn(ii) complexes of polynucleating Mannich base ligand show significant catalytic oxidase activities and are antiferromagnetically coupled which is rationalized by DFT calculations.

Funder

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01567A

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