Tetranuclear NiII-Mannich base complex with oxygenase, water splitting and ferromagnetic and antiferromagnetic coupling properties

Author:

Patra Arka1,Das Avijit1,Sarkar Abhimanyu1,Gómez-García Carlos J.2ORCID,Sinha Chittaranjan1ORCID

Affiliation:

1. Department of Chemistry, Jadavpur University, Kolkata-700032, India

2. Departmento de Química Inorgánica, Universidad de Valencia, C/Dr. Moliner 50, 46100 Burjasot, Valencia, Spain

Abstract

The rhombic-tetranuclear NiII [Ni4(L)21,1Cl)2(H2O)4]2+ (1) complex with two types of Ni(ii) pairs shows ferro and antiferromagnetic exchange and catalytic oxidase activities of catechol and o-aminophenol. The complex shows OER and HER activities.

Funder

Jadavpur University

Council of Scientific and Industrial Research, India

University Grants Commission

Generalitat Valenciana

Fourth Framework Programme

Human Resource Development Group

Publisher

Royal Society of Chemistry (RSC)

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