Insertion of germanium atoms in high-nuclearity rhodium carbonyl compounds: synthesis, characterization and preliminary biological activity of the heterometallic [Rh13Ge(CO)25]3−, [Rh14Ge2(CO)30]2− and [Rh12Ge(CO)27]4− clusters
Author:
Affiliation:
1. Department of Industrial Chemistry “Toso Montanari”
2. University of Bologna
3. I-40136 Bologna
4. Italy
5. Institut des Sciences et Ingénierie Chimiques
6. Ecole Polytechnique Fédérale de Lausanne (EPFL)
7. CH-1015 Lausanne
8. Switzerland
Abstract
The reaction of [Rh7(CO)16]3− with Ge2+ salts led to the first Rh carbonyl clusters with interstitial Ge atoms.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT02466A
Reference55 articles.
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3. Isolation and Structural Characterization of a Mackay 55-Metal-Atom Two-Shell Icosahedron of Pseudo-Ih Symmetry, Pd55L12(μ3-CO)20 (L = PR3, R = Isopropyl): Comparative Analysis with Interior Two-Shell Icosahedral Geometries in Capped Three-Shell Pd145, Pt-Centered Four-Shell Pd–Pt M165, and Four-Shell Au133 Nanoclusters
4. Structures of large transition metal clusters
5. Metal-metal and metal-carbon bond energy terms for the rhodium carbonyl clusters Rh4(CO)12 and Rh6(CO)16
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