Atomically precise rhodium–indium carbonyl nanoclusters: synthesis, characterization, crystal structure and electron-sponge features-Reference-Cited by-同舟云学术

Atomically precise rhodium–indium carbonyl nanoclusters: synthesis, characterization, crystal structure and electron-sponge features

Published:2024 Issue: Volume: Page:
ISSN:2040-3364
Container-title:Nanoscale
language:en
Short-container-title:Nanoscale

Author:

Bussoli Guido¹,Boccalini Alberto¹,Bortoluzzi Marco²^ORCID,Cesari Cristiana¹^ORCID,Iapalucci Maria Carmela¹,Funaioli Tiziana³,Scorzoni Giorgia¹^ORCID,Zacchini Stefano¹^ORCID,Ruggieri Silvia¹⁴^ORCID,Femoni Cristina¹^ORCID

Affiliation:

1. Department of Industrial Chemistry “Toso Montanari”, University of Bologna, Via Gobetti 85, 40129 Bologna, Italy

2. Department of Molecular Sciences and Nanosystems, Ca’ Foscari University of Venice, Via Torino 155, 30170 Mestre, VE, Italy

3. Department of Chemistry and Industrial Chemistry, University of Pisa, Via Moruzzi 13, 56124 Pisa, Italy

4. Laboratory of Luminescent Materials, Department of Biotechnology, University of Verona and INSTM, UdR Verona, Strada Le Grazie 15, 37134 Verona, Italy

Abstract

The reactivity of [Rh7(CO)16]3− with InCl3 led to the isolation of three new clusters, including [Rh12In(CO)28]3−, which extends the [Rh12E(CO)27]n− series (E = Sn, Ge, Sb, Bi). Its multivalence has been experimentally and theoretically unravelled.

Funder

Università di Bologna

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NR/D4NR02922D

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