Insight into the pseudo π-hole interactions in the M3H6⋯(NCF)n (M = C, Si, Ge, Sn, Pb; n = 1, 2, 3) complexes-Reference-Cited by-同舟云学术

Insight into the pseudo π-hole interactions in the M3H6⋯(NCF)n (M = C, Si, Ge, Sn, Pb; n = 1, 2, 3) complexes

Published:2016 Issue:35 Volume:18 Page:24672-24680
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Li Wei¹²³⁴⁵,Zeng Yanli¹²³⁴⁵,Li Xiaoyan¹²³⁴⁵,Sun Zheng¹²³⁴⁵,Meng Lingpeng¹²³⁴⁵

Affiliation:

1. Institute of Computational Quantum Chemistry

2. College of Chemistry and Material Science

3. Hebei Normal University

4. Shijiazhuang 050024

5. P. R. China

Abstract

For cyclopropane and its derivatives M₃H₆ (M = C, Si, Ge, Sn, Pb), “pseudo π-hole” regions above and below the M–M–M three-membered ring have been discovered, and pseudo π-hole interactions between M₃H₆ and F–CN have been designed and investigated.

Funder

Natural Science Foundation of Hebei Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP03713E

Reference62 articles.

1. Noncovalent Interactions: A Challenge for Experiment and Theory

2. Halogen bonding: the σ-hole