Carbon dioxide binding at a Ni/Fe center: synthesis and characterization of Ni(η1-CO2-κC) and Ni-μ-CO2-κC:κ2O,O′-Fe
Author:
Affiliation:
1. Department of Chemistry
2. Korea Advanced Institute of Science and Technology (KAIST)
3. Daejeon 34141
4. Republic of Korea
Abstract
A heterobimetallic Ni-μ-CO2-κC:κ2O,O′-Fe species reminiscent of the CODH active site was synthesized, helping to elucidate the role of the unique iron.
Funder
National Research Foundation of Korea
KAIST
Korea Institute of Science and Technology
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/SC/C6SC03450K
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