CO<sub>2</sub> cleavage by tantalum/M (M = iridium, osmium) heterobimetallic complexes-Reference-Cited by-同舟云学术

CO₂ cleavage by tantalum/M (M = iridium, osmium) heterobimetallic complexes

Published:2024 Issue:61 Volume:60 Page:7878-7881
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Lachguar Abdelhak¹,Ye Christopher Z.²³^ORCID,Kelly Sheridon N.²³^ORCID,Jeanneau Erwann⁴,Del Rosal Iker⁵^ORCID,Maron Laurent⁵^ORCID,Veyre Laurent¹,Thieuleux Chloé¹^ORCID,Arnold John²³^ORCID,Camp Clément¹^ORCID

Affiliation:

1. Laboratory of Catalysis, Polymerization, Processes and Materials (CP2M UMR 5128) CNRS, Universite Claude Bernard Lyon 1, CPE-Lyon, Institut de Chimie de Lyon, 43 Bvd du 11 Novembre 1918, 69616 Villeurbanne, France

2. Department of Chemistry, University of California, Berkeley, California 94720, USA

3. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA

4. Centre de Diffractométrie Henri Longchambon, Universite Claude Bernard Lyon 1, 5 Rue de la Doua, 69100 Villeurbanne, France

5. Université de Toulouse, CNRS, INSA, UPS, UMR5215, LCPNO, 135 Avenue de Rangueil, F-31077 Toulouse, France

Abstract

A novel Ta/Os complex [Ta(CH2tBu)3(μ-H)3OsCp*], and its iridium analogue [Ta(CH2tBu)3(μ-H)2IrCp*], efficiently cleave CO2 under mild conditions, forming tantalum oxo species and CpIr(CO)H2 or CpOs(CO)H3.

Funder

European Research Council

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC02207F

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