Synthesis of model humic substances: a mechanistic study using controllable H/D exchange and Fourier transform ion cyclotron resonance mass spectrometry

Author:

Zherebker Alexander Ya.1234,Airapetyan David1234,Konstantinov Andrey I.1234,Kostyukevich Yury I.56478,Kononikhin Alexey S.56478,Popov Igor A.56478,Zaitsev Kirill V.1234,Nikolaev Eugene N.56478,Perminova Irina V.1234

Affiliation:

1. Department of Chemistry

2. Lomonosov Moscow State University

3. 119991 Moscow

4. Russia

5. Institute for Energy Problems of Chemical Physics of RAS

6. 119334 Moscow

7. Moscow Institute of Physics and Technology

8. 141700 Moscow Region

Abstract

The exact structural formulas of model humic substances are identified using controllable H/D exchanged coupled to FTMS.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Electrochemistry,Spectroscopy,Environmental Chemistry,Biochemistry,Analytical Chemistry

Reference47 articles.

1. THE PRINCIPLES OF HUMIC SUBSTANCES

2. F. J. Stevenson , Humus Chemistry: Genesis, Composition, Reactions, John Wiley & Sons, New York, 2nd edn, 1994

3. G. W. Bailey , L. G.Akim and S. M.Shevchenko, Humic Substances, in Humic substances and chemical contaminants, ed. C. E. Clapp, M. H. B. Hayes, N. Senesi, P. R. Bloom and P. M. Jardine, Soil Science Society of America, Madison, WI, 2001, pp. 41–73

4. N. A. Kulikova , E. V.Stepanova and O. V.Koroleva, in Use of humic substances to remediate polluted environments: from theory to practice, ed. I. V. Perminova, K. Hatfield, N. Hertkorn, NATO Science Series: IV: Earth and Environmental Sciences, Springer Verlag, Dordrecht, The Netherlands, 2004, vol. 52, p. 285

5. R. Kloecking and B.Helbig, in Biopolymers for medical and pharmaceutical applications, ed. A. Steinbüchel and R. H. Marchessault, Wiley-VCH Verlag GmbH, Weinheim, 2005, p. 3

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