Redox-induced reversible [2 + 2] cycloaddition of an etheno-fused diporphyrin-Reference-Cited by-同舟云学术

Redox-induced reversible [2 + 2] cycloaddition of an etheno-fused diporphyrin

Published:2021 Issue:14 Volume:12 Page:5224-5229
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Miyagawa Kazuya¹²³⁴⁵,Hisaki Ichiro⁶⁷⁸⁵^ORCID,Fukui Norihito¹²³⁴⁵,Shinokubo Hiroshi¹²³⁴⁵^ORCID

Affiliation:

1. Department of Molecular and Macromolecular Chemistry

2. Graduate School of Engineering

3. Nagoya University

4. Nagoya 464-8603

5. Japan

6. Graduate School of Engineering Science

7. Osaka University

8. Osaka 560-8531

Abstract

A four-electron oxidation of an X-shaped tetraporphyrin affords stable etheno-fused diporphyrin dications through double C–C bond cleavage. The reduction of the dication recovers the tetraporphyrin via a thermal [2 + 2] cycloaddition.

Funder

Japan Society for the Promotion of Science

Sumitomo Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC00438G

Reference55 articles.

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