Unprecedented diastereoselective generation of chiral-at-metal, half sandwich Ir(iii) and Rh(iii) complexes via anomeric isomerism on “sugar-coated” N-heterocyclic carbene ligands
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2011/DT/C0DT01634A
Reference24 articles.
1. Half-Sandwich Complexes with Aminocarboxylate Ligands and Their Use as Enantioselective Hydrogen Transfer Catalysts
2. Chiral organometallic half-sandwich complexes with defined metal configuration
3. Half-sandwich iridium complexes—Synthesis and applications in catalysis
4. Diastereoselective Preparation of Chiral-at-Metal Organometallic Complexes Using a Chelating Sulfoxide−Carboxylate Ligand
5. C−H Activation of Phenyl Imines and 2-Phenylpyridines with [Cp*MCl2]2 (M = Ir, Rh): Regioselectivity, Kinetics, and Mechanism
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