Intramolecular C–H insertion vs. Friedel–Crafts coupling induced by silyl cation-promoted C–F activation
Author:
Affiliation:
1. Department of Chemistry
2. University of Zürich Winterthurerstrasse 190
3. 8057 Zürich
4. Switzerland
5. School of Pharmaceutical Science and Technology
Abstract
Silyl cation-promoted aryl C–F activation can lead to formal C–H activation and the formation of new C(ar)–C(alkyl) bonds.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/QO/C5QO00170F
Reference22 articles.
1. Main-Group Lewis Acids for C–F Bond Activation
2. C−F Bond Activation in Organic Synthesis
3. Room-Temperature Catalytic Hydrodefluorination of C(sp3)−F Bonds
4. Hydrodefluorination of Perfluoroalkyl Groups Using Silylium-Carborane Catalysts
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