Efficient CO2 fixation into cyclic carbonates catalyzed by NNO-scorpionate zinc complexes

Author:

Sobrino Sonia12345ORCID,Navarro Marta678910ORCID,Fernández-Baeza Juan12345ORCID,Sánchez-Barba Luis F.678910ORCID,Garcés Andrés678910ORCID,Lara-Sánchez Agustín12345ORCID,Castro-Osma José A.111121314ORCID

Affiliation:

1. Universidad de Castilla-La Mancha

2. Departamento de Química Inorgánica

3. Orgánica y Bioquímica

4. Centro de Innovación en Química Avanzada (ORFEO-CINQA) Campus Universitario

5. 13071-Ciudad Real

6. Universidad Rey Juan Carlos

7. Departamento de Biología y Geología

8. Física y Química Inorgánica

9. Móstoles-28933-Madrid

10. Spain

11. Departamento de Química Inorgańica

12. Orgańica y Bioquímica

13. Centro de Innovación en Química Avanzada (ORFEO–CINQA)

14. Facultad de Farmacia

Abstract

Chiral bifunctional and bicomponent NNO-scorpionate zinc-based catalysts have been developed for the fixation of CO2 into cyclic carbonates with broad substrate scope and functional group tolerance under mild and solvent-free conditions.

Funder

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference79 articles.

1. Carbon dioxide as chemical feedstock , ed. M. Aresta , Wiley-VCH , Weinheim , 2010

2. Chemical Technologies for Exploiting and Recycling Carbon Dioxide into the Value Chain

3. Carbon Dioxide Recycling: Emerging Large-Scale Technologies with Industrial Potential

4. New and Future Developments in Catalysis , ed. S. L. Suib , Elsevier , Amsterdam , 2013

5. Closing the loop: captured CO2 as a feedstock in the chemical industry

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