A four-parameter system for rationalising the electronic properties of transition metal–radical ligand complexes-Reference-Cited by-同舟云学术

A four-parameter system for rationalising the electronic properties of transition metal–radical ligand complexes

Published:2020 Issue:28 Volume:49 Page:9735-9742
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mews N. M.¹²³⁴,Reimann M.⁵⁶⁷⁸⁴^ORCID,Hörner G.⁹¹⁰¹¹⁴^ORCID,Kaupp M.⁵⁶⁷⁸⁴^ORCID,Schubert H.¹²³⁴,Berkefeld A.¹²³⁴^ORCID

Affiliation:

1. Institut für Anorganische Chemie

2. Eberhard Karls Universität Tübingen

3. 72076 Tübingen

4. Germany

5. Institut für Chemie

6. Theoretical Chemistry–Quantum Chemistry

7. Technische Universität Berlin

8. 10623 Berlin

9. Anorganische Chemie IV

10. Universität Bayreuth

11. 95440 Bayreuth

Abstract

A heuristic four-parameter scheme captures and predicts the electronic properties of radical-ligand transition metal compounds, overcoming ligand specific descriptions.

Funder

Baden-Württemberg Stiftung

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT02237C

Reference52 articles.

1. Non-innocent ligands in bioinorganic chemistry—An overview

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5. Redox-ligand sustains controlled generation of CF3 radicals by well-defined copper complex

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