Redox-ligand sustains controlled generation of CF3 radicals by well-defined copper complex-Reference-Cited by-同舟云学术

Redox-ligand sustains controlled generation of CF3 radicals by well-defined copper complex

Published:2016 Issue:3 Volume:7 Page:2030-2036
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Jacquet Jérémy¹²³⁴,Blanchard Sébastien¹²³⁴,Derat Etienne¹²³⁴,Desage-El Murr Marine¹²³⁴,Fensterbank Louis¹²³⁴

Affiliation:

1. Institut Parisien de Chimie Moléculaire

2. UMR CNRS 8232

3. Sorbonne Universités UPMC Univ Paris 06

4. France

Abstract

Cooperative catalysis involving copper(ii) complex bearing redox ligands allows generation of CF˙3 radicals through ligand-based SET while metallic oxidation state is preserved.

Funder

Université Pierre et Marie Curie

Centre National de la Recherche Scientifique

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC03636D

Reference78 articles.

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5. Radical Ligands Confer Nobility on Base-Metal Catalysts

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